Between 11kv and 25kv, it's not much difference, though if you want to be really pendantic, the current at the pan is about 1/2 with 25kv, and theoretically it can handle more. More significant would be dumping 25hz, which would shave a bit of weight off of the cars, since 60hz transformers are lighter (this is why aircraft are 400hz - it allows even lighter transformers, and smaller filters for DC supplies). Frequency changes mean little/nothing to AC traction equipment (it's rectified to DC then inverted anyway - as long as the filters can cope with the lower frequency, it's ok), but voltage changes need to be handled somehow. Typically, this is a tap changer on the primary, though there's a few ways to do it. GE stuff tended to have two primaries - they would run in series on 25kv, parallel on 11kv, I think ASEA/ABB uses a tapped primary. In theory, it could be handled on the secondary side as a function of the DC conversion equipment (much like your computer's "international" power supply), though I don't know if this is done in practice. That'd mean no tap changers and their maintenance.
On Silverliners and pre rebuilt Arrows, frequency changes could screw things up because it messed with the firing of the ignitrons - though I'm not sure how GE compensated for this and if it was automagic. It wasn't on the E-60's, I'm not sure about the GE equipped Metroliners (which were Silverliner derrived and 25kv/60hz capable)
Anyway, 11kv/25kv shouldn't "feel" any different, though I wouldn't be too surprised if 60hz / 25 hz did slightly.